Carbon Sequestration

Technarch

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Algae have been explored for biofuels, and even though electrification almost certainly wins in most of those use cases, the oil you get is still going to be pretty stable. As far as I understand it, oil can't decay any further anaerobically (otherwise it would be consumed in the ground). So if you have some way to go from biomass to hydrocarbons, and then store the hydrocarbons in salt domes or similar, it should stay buried for a usefully long time.

... until someone finds and taps those stores, certainly. A dense energy source, in concentrated, easily extracted form, is how we got ourselves collectively into this problem in the first place. "Making oil and putting it in the ground" doesn't sound likely to keep it there. I'm inclined to make use of that synthetic oil for energy, at least during the transition.

The issue with algae fuels in the past has been cost competitiveness with fossil fuels. Processing the algae to make usable diesel is labor intensive. If you're just going to bury the algae, though, that might be doable for the cost of a carbon credit. But you still have to feed the algae.
 

Megalodon

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... until someone finds and taps those stores, certainly. A dense energy source, in concentrated, easily extracted form, is how we got ourselves collectively into this problem in the first place. "Making oil and putting it in the ground" doesn't sound likely to keep it there. I'm inclined to make use of that synthetic oil for energy, at least during the transition.
I mean if the worst case is carbon neutral oil that's not so bad, I just don't know that it would be competitive as an energy source. Maybe for something like aviation where it's extremely difficult to get the needed energy density any other way.

With the various biological methods, are there concerns about other nutrients? Trees take more than just carbon dioxide to grow, and that's normally released back into the ecosystem - but it won't be with a lot of the burial methods proposed.
With algae I believe if properly processed you get triglycerides, which have only C, H, and a little bit of O. Everything else can be recovered and fed back to the next generation of algae.

Much of the energy cost comes from having to separate the oils from the water sufficiently to avoid problems in engines, and it seems like that could be abbreviated or skipped. I believe triglycerides are insoluble in water so possibly it would be enough to allow them to separate by density. Loss of some amount of water to the process shouldn't matter much, especially if it's seawater.
 

TSBasilisk

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Algae have been explored for biofuels, and even though electrification almost certainly wins in most of those use cases, the oil you get is still going to be pretty stable. As far as I understand it, oil can't decay any further anaerobically (otherwise it would be consumed in the ground). So if you have some way to go from biomass to hydrocarbons, and then store the hydrocarbons in salt domes or similar, it should stay buried for a usefully long time.

... until someone finds and taps those stores, certainly. A dense energy source, in concentrated, easily extracted form, is how we got ourselves collectively into this problem in the first place. "Making oil and putting it in the ground" doesn't sound likely to keep it there. I'm inclined to make use of that synthetic oil for energy, at least during the transition.

The issue with algae fuels in the past has been cost competitiveness with fossil fuels. Processing the algae to make usable diesel is labor intensive. If you're just going to bury the algae, though, that might be doable for the cost of a carbon credit. But you still have to feed the algae.
The project I posted a while back was focused solely on sequestration. Upwelling, nutrient-rich ocean water is pumped into pools on a stretch of land where a local algae species is bred. The algae are then extracted from the water and dried before being buried in dry soul, which limits decomposition. The water returned to the ocean may have lost the nutrients, but the process reduces the acidity of the water which is a net plus.

Of course the same idea could also be used to produce algae food crops rather than for sequestration.
 

demultiplexer

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Algae have been explored for biofuels, and even though electrification almost certainly wins in most of those use cases, the oil you get is still going to be pretty stable. As far as I understand it, oil can't decay any further anaerobically (otherwise it would be consumed in the ground). So if you have some way to go from biomass to hydrocarbons, and then store the hydrocarbons in salt domes or similar, it should stay buried for a usefully long time.

... until someone finds and taps those stores, certainly. A dense energy source, in concentrated, easily extracted form, is how we got ourselves collectively into this problem in the first place. "Making oil and putting it in the ground" doesn't sound likely to keep it there. I'm inclined to make use of that synthetic oil for energy, at least during the transition.

The issue with algae fuels in the past has been cost competitiveness with fossil fuels. Processing the algae to make usable diesel is labor intensive. If you're just going to bury the algae, though, that might be doable for the cost of a carbon credit. But you still have to feed the algae.

Algae are actually a really rich source of oils, it's better in many ways than other crops we grow for biodiesel! Purely speaking economically, algae are a better choice than almost anything else. Bioengineered strains have up to 60% by dry weight in oil and require less post-processing than oil crops - those tend to peter out at around 25-30% by weight (and require freshwater, fertilizers, relatively high fossil fuel investment, etc.)

But as is often the case, biodiesel by and large isn't made for environmental or efficiency reasons, it's a political thing. It gives farmers something to do, farmers who otherwise would be producing surplus stuff and driving down market prices. It's also an energy independence thing spurred on by the first oil crisis.

As such, a lot of biofuel endeavors are highly subsidized and an integral part of the economy competing with actual solutions for climate change. That hinders the investment into and development of things like algae-based oil production. Which as it looks now is one of only 2 viable ways to decarbonize aviation and part of global shipping.
 

Technarch

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Last I checked, the most promising development was with strains of algae that actually exude oil, raising the possibility that the oil could be separated from the algae without killing it. But those strains were relatively slow growing, and they couldn't find a way to "milk" the algae that was cost effective--it had to be rinsed in some kind of fairly exotic solvent.

The other issue with farming algae that I noticed was the difficulty of preventing other algaes from invading your algae ponds. Weeding your garden is one thing, picking bad algae out of the good algae is something else. So now instead of plastic-lined pits or raceway ponds, you're looking at growing algae in sealed reactors, with all the pumps and plumbing that entails.
 

Megalodon

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Last I checked, the most promising development was with strains of algae that actually exude oil, raising the possibility that the oil could be separated from the algae without killing it. But those strains were relatively slow growing, and they couldn't find a way to "milk" the algae that was cost effective--it had to be rinsed in some kind of fairly exotic solvent.
This is one upside for using it for carbon sequestration though. You may not have to extract the oil to immobilize the carbon for a useful amount of time. Using it as fuel requires purity sufficient to work in engines, but for sequestration you only need it to be in a state where it won't decompose anaerobically releasing methane. Just evaporating the water leaving a salty oily brine may be sufficient. That can then be disposed of in salt domes or old oil wells or some other suitable location.
 
... until someone finds and taps those stores, certainly. A dense energy source, in concentrated, easily extracted form, is how we got ourselves collectively into this problem in the first place. "Making oil and putting it in the ground" doesn't sound likely to keep it there. I'm inclined to make use of that synthetic oil for energy, at least during the transition.

With the various biological methods, are there concerns about other nutrients? Trees take more than just carbon dioxide to grow, and that's normally released back into the ecosystem - but it won't be with a lot of the burial methods proposed.
As noted before, the "bury carbon in the ground" method I like is biochar - preferably mixed with livestock waste (manure, urine) and used as a soil amendment in areas where it will improve soil fertility. After it's mixed into soil, re-extraction to burn as fuel is unlikely to ever be cost effective.
 

dyungim

Smack-Fu Master, in training
56
As I sit here in the middle of the worst heatwave in Europe's history and watch the river under my windows literally carry my country's glaciers away I come to an inescapable conclusion.

Politics failed the fight against climate change. Humans failed.

While we are finally seeing some significant traction all over the world about taking this fight seriously, this will undoubtedly not be global enough nor fast enough to get us where we need to be : Net Zero.

I don't think we can get there in "time", there will always be countries who refuse to change and industries who can't change (transcontinental flight is just not going to be carbon neutral in my lifetime for example) so we need science and technology to bail us out, again.

We need, scalable, economical carbon sequestration so that we can compensate the emissions that we will just never be able to stop entirely, probably help compensate all the countries headed by idiots who are not transitioning and, pipe dream, maybe, someday start extracting more CO2 than we put into the atmosphere to reverse over time the damage we did.

So I was wondering where do we stand on that front today? I've seen the usual rosy newspaper article on startups experimenting with this and that but I'm old enough to not put much stock into such articles. It's easy to look good in front of a journalist, it's really hard to build something that scales and is economically viable...

So I thought I'd start a thread here. Am I just being delusional in thinking such a technology is realistic at all? If not, what are the different technological paths being researched and how promising/challenging are they?

https://www.globalcarbonproject.org...limits to negative CO2 emissions.NatureCC.pdf
The technologies exist and many of them are feasible and rather affordable. The challenge is that the ones which are most feasible also require considerable land use, which is typically more politics constrained than just manufacturing more widgets.

Economically speaking it's not a big deal. The level of coordination, however, is probably similar to what's required to build a spaceport in every major city.
 

Auguste_Fivaz

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In the Guardian today was an article "Fossil fuel producers must be forced to ‘take back’ carbon, say scientists," an idea I had never hear of before. I'd imagine some of the more advanced thinking activists already have been down this path, but at least the paper cited has the Oxford imprimatur. But, as Prof. Barnhart in the "TDTESS" (1951) says, "we scientists are often ignored or misunderstood," so it is hard to tell what if any impact this might have against mighty petrol who, I would hazard, might not want to trade in this market at all and scoff at the idea as unrealistic.
 

dzid

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I'm unsure if this is the best place to post this. The subject isn't a specific carbon sequestration method, but rather research (note: abstract only; non-public) that might help in their development.

From phys.org: Permafrost study finds abrupt thaw accelerates soil phosphorus cycling, offsetting carbon release

From the article:
In this new study published in Nature Climate Change, the researchers investigated whether and how abrupt permafrost thaw affects soil phosphorus transformation processes and plant phosphorus uptake, presenting clear evidence that it accelerates soil phosphorus cycling.
...
Although permafrost thaw is generally considered to convert the frozen carbon pools from stable sinks into potential "carbon bombs," this study shows that the same process also accelerates ecosystem phosphorus cycling, thereby enhancing ecosystem primary productivity and carbon sequestration.

These findings provide critical insights for accurately predicting the fate of permafrost carbon and for developing strategies to mitigate its impacts in climate-sensitive regions.

Presumably, this means that it may be possible to develop strategies for what plants might be most beneficial to grow as permafrost thaws in response to climate change.